10.26165/JUELICH-DATA/D8GNJM Marie S. Sättele(University of Tübingen, Germany)Andreas Windischbacher(University of Graz, Austria)Larissa Egger(University of Graz, Austria)Anja Haags(Forschungszentrum Jülich, Germany)Philipp Hurdax(University of Graz, Austria)Hans Kirschner(Physikalisch-Technische Bundesanstalt, Germany)Alexander Gottwald0000-0003-2810-7419(Physikalisch-Technische Bundesanstalt, Germany)Mathias Richter(Physikalisch-Technische Bundesanstalt, Germany)Franco̧is C. Bocquet0000-0002-9471-4439(Forschungszentrum Jülich, Germany)Serguei Soubatch0000-0002-1455-0260(Forschungszentrum Jülich, Germany)F. Stefan Tautz0000-0003-3583-2379(Forschungszentrum Jülich, Germany)Holger F. Bettinger(University of Tübingen, Germany)Heiko Peisert(University of Tübingen, Germany)Thomas Chassé(University of Tübingen, Germany)Michael G. Ramsey(University of Graz, Austria)Peter Puschnig(University of Graz, Austria)Georg Koller0000-0001-7741-2394(University of Graz, Austria) Jülich DATA 2021 We provide here the raw data used to produce the figures in the publication Marie S. Sättele et al., Going beyond Pentacene: Photoemission Tomography of a Heptacene Monolayer on Ag(110), J. Phys. Chem. C, dx.doi.org/10.1021/acs.jpcc.0c09062 All metadata necessary to analyze the data are contained in the files. 14211-Ag110-20Ke-32Ke---EDC.txt, 14212-Ag110-20Ke-32Ke---EDC.txt Angle-resolved photoemission spectroscopy data as acquired, used to produce figure 2a. 14208-Ag110--35Pe---Fermi.txt, 14209-Ag110--35Pe---Fermi.txt*, 14210-Ag110--35Pe---Fermi.txt, 14214-Ag110--35Pe---Fermi.txt Angle-resolved photoemission spectroscopy data as acquired, used to produce figures 1a*, 3b, and 4 (heptacene orbitals). 6657-Ag110--30Pe-30Ke-Azimuth.txt, 6658-Ag110--30Pe-30Ke-Azimuth.txt*, 6659-Ag110--30Pe-30Ke-Azimuth.txt, 6660-Ag110--30Pe-30Ke-Azimuth.txt Angle-resolved photoemission spectroscopy data as acquired, used to produce figure 4 (pentacene orbitals). Analysis program compatible with the format of these files can be requested from s.subach@fz-juelich.de. Subach, Sergey(Forschungszentrum Jülich, Germany)Georg Koller(University of Graz, Austria)