{"dcterms:modified":"2024-03-19","dcterms:creator":"A Dataverse Instance","@type":"ore:ResourceMap","@id":"https://data.fz-juelich.de/api/datasets/export?exporter=OAI_ORE&persistentId=doi:10.26165/JUELICH-DATA/0GQJFC","ore:describes":{"Title":"Replication NMR Data for: In operando NMR investigations of the aqueous electrolyte chemistry during electrolytic CO2 reduction","fzj:Institute":"IEK-9","fzj:PoF IV topic":"Power-based Fuels and Chemicals (POF4-1232)","Author":[{"author:Name":"Jovanovic, Sven","author:Affiliation":"IEK-9 Forschungszentrum Jülich","Identifier Scheme":"ORCID","Identifier":"https://orcid.org/0000-0002-1227-4936"},{"author:Name":"Jakes, Peter","author:Affiliation":"IEK-9 Forschungszentrum Jülich","Identifier Scheme":"ORCID","Identifier":"https://orcid.org/0000-0002-5187-4969"},{"author:Name":"Merz, Steffen","author:Affiliation":"IEK-9 Forschungszentrum Jülich","Identifier Scheme":"ORCID","Identifier":"https://orcid.org/0000-0002-2163-5027"},{"author:Name":"Daniel, Davis Thomas","author:Affiliation":"IEK-9 Forschungszentrum Jülich, ITMC RWTH Aachen","Identifier Scheme":"ORCID","Identifier":"https://orcid.org/0000-0001-7035-3416"},{"author:Name":"Eichel, Rüdiger-A.","author:Affiliation":"IEK-9 Forschungszentrum Jülich, IPC RWTH Aachen","Identifier Scheme":"ORCID","Identifier":"https://orcid.org/0000-0002-0013-6325"},{"author:Name":"Granwehr, Josef","author:Affiliation":"IEK-9 Forschungszentrum Jülich, ITMC RWTH Aachen","Identifier Scheme":"ORCID","Identifier":"https://orcid.org/0000-0002-9307-1101"}],"citation:Contact":[{"datasetContact:Name":"Jovanovic, Sven","datasetContact:Affiliation":"IEK-9 Forschungszentrum Jülich","datasetContact:E-mail":"s.jovanovic@fz-juelich.de"},{"datasetContact:Name":"Granwehr, Josef","datasetContact:Affiliation":"IEK-9 Forschungszentrum Jülich, ITMC RWTH Aachen","datasetContact:E-mail":"j.granwehr@fz-juelich.de"}],"citation:Description":{"dsDescription:Text":"NMR raw data of 13C and 23Na experiments for the in operando CO2 electrolysis experiments in aqueous HCO3- electrolyte, as described in the publication. \r\nThe in operando electrolysis experiments were divided into 3 stages: open circuit voltage (OCV), chronoamperometry (CA) at a constant voltage slightly below the electrolysis potential of -1.1 V vs. Ag/AgCl, and finally the chronopotentiometry (CP) at a constant current density of -10 µA/cm², where the electrolysis reaction took place. \r\nFor each stage, 12 hours of spectra were recorded (Spectra recording). Afterwards, saturation recovery and CPMG experiments were performed for the determination of T1 and T2, respectively. In case of the 13C experiments, additional 1D exchange spectroscopy (EXSY) experiments were performed for the determination of the CO2/HCO3- exchange rate. \r\n13C experiments were performed at two different magnetic fields (14.1 T and 9.4 T), 23Na at a single magnetic field (14.1 T)."},"Subject":"Chemistry","Related Publication":{"Citation":"Jovanovic, S., Jakes, P., Merz, S. et al. In operando NMR investigations of the aqueous electrolyte chemistry during electrolytic CO2 reduction. Commun Chem 6, 268 (2023). https://doi.org/10.1038/s42004-023-01065-3","ID Type":"doi","ID Number":"https://doi.org/10.1038/s42004-023-01065-3","URL":"https://www.nature.com/articles/s42004-023-01065-3"},"Language":"English","citation:Producer":{"producer:Name":"Jovanovic, Sven","producer:Affiliation":"IEK-9 Forschungszentrum Jülich","producer:URL":"https://www.fz-juelich.de/profile/jovanovic_s"},"citation:Production Place":"IEK-9 Forschungszentrum Jülich GmbH","Contributor":[{"contributor:Type":"Data Collector","contributor:Name":"Jovanovic, Sven"},{"contributor:Type":"Researcher","contributor:Name":"Jakes, Peter"},{"contributor:Type":"Researcher","contributor:Name":"Merz, Steffen"},{"contributor:Type":"Researcher","contributor:Name":"Daniel, Davis Thomas"},{"contributor:Type":"Supervisor","contributor:Name":"Eichel, Rüdiger-A."},{"contributor:Type":"Supervisor","contributor:Name":"Granwehr, Josef"}],"Grant Information":[{"grantNumber:Grant Agency":"BMBF","grantNumber:Grant Number":"03SFK2A"},{"grantNumber:Grant Agency":"DFG","grantNumber:Grant Number":"390919832"}],"citation:Depositor":"Jovanovic, Sven","Deposit Date":"2024-03-14","Kind of Data":"NMR raw data recorded in topspin","Software":{"software:Name":"Topspin","software:Version":"3.2"},"@id":"doi:10.26165/JUELICH-DATA/0GQJFC","@type":["ore:Aggregation","schema:Dataset"],"schema:version":"1.0","schema:datePublished":"2024-03-19","schema:name":"Replication NMR Data for: In operando NMR investigations of the aqueous electrolyte chemistry during electrolytic CO2 reduction","schema:dateModified":"2024-03-19 10:36:56.774","dvcore:fileTermsOfAccess":{"dvcore:fileRequestAccess":false},"schema:includedInDataCatalog":"Spectroscopy","ore:aggregates":[{"schema:name":"NMR Data in operando CO2 electrolysis.zip","dvcore:restricted":false,"schema:version":2,"dvcore:datasetVersionId":480,"@id":"https://data.fz-juelich.de/file.xhtml?fileId=14557","schema:sameAs":"https://data.fz-juelich.de/api/access/datafile/14557","@type":"ore:AggregatedResource","schema:fileFormat":"application/zip","dvcore:filesize":431366283,"dvcore:storageIdentifier":"s3://juelich_data:18e51bd76e3-989221fc1464","dvcore:rootDataFileId":-1,"dvcore:checksum":{"@type":"SHA-256","@value":"787215c5a3d0fddf95452a104b2d86fcb04dcb25f75fbd1909b8d401bf8a6486"}}],"schema:hasPart":["https://data.fz-juelich.de/file.xhtml?fileId=14557"]},"@context":{"Author":"http://purl.org/dc/terms/creator","Citation":"http://purl.org/dc/terms/bibliographicCitation","Contributor":"http://purl.org/dc/terms/contributor","Deposit Date":"http://purl.org/dc/terms/dateSubmitted","Grant Information":"https://schema.org/sponsor","ID Number":"http://purl.org/spar/datacite/ResourceIdentifier","ID Type":"http://purl.org/spar/datacite/ResourceIdentifierScheme","Identifier":"http://purl.org/spar/datacite/AgentIdentifier","Identifier Scheme":"http://purl.org/spar/datacite/AgentIdentifierScheme","Kind of Data":"http://rdf-vocabulary.ddialliance.org/discovery#kindOfData","Language":"http://purl.org/dc/terms/language","Related Publication":"http://purl.org/dc/terms/isReferencedBy","Software":"https://www.w3.org/TR/prov-o/#wasGeneratedBy","Subject":"http://purl.org/dc/terms/subject","Title":"http://purl.org/dc/terms/title","URL":"https://schema.org/distribution","author":"https://dataverse.org/schema/citation/author#","citation":"https://dataverse.org/schema/citation/","contributor":"https://dataverse.org/schema/citation/contributor#","datasetContact":"https://dataverse.org/schema/citation/datasetContact#","dcterms":"http://purl.org/dc/terms/","dsDescription":"https://dataverse.org/schema/citation/dsDescription#","dvcore":"https://dataverse.org/schema/core#","fzj":"https://jugit.fz-juelich.de/fdm/schemas","grantNumber":"https://dataverse.org/schema/citation/grantNumber#","ore":"http://www.openarchives.org/ore/terms/","producer":"https://dataverse.org/schema/citation/producer#","schema":"http://schema.org/","software":"https://dataverse.org/schema/citation/software#"}}