{"dcterms:modified":"2024-01-26","dcterms:creator":"A Dataverse Instance","@type":"ore:ResourceMap","@id":"https://data.fz-juelich.de/api/datasets/export?exporter=OAI_ORE&persistentId=doi:10.26165/JUELICH-DATA/CYHXRM","ore:describes":{"Title":"Replication Data for: Space charge governs the kinetics of metal exsolution","fzj:Institute":["IEK-1","PGI-7"],"fzj:PoF IV topic":"Not covered by a PoF IV topic (POF4-899)","Author":[{"author:Name":"Weber, Moritz","author:Affiliation":"Forschungszentrum Jülich","Identifier Scheme":"ORCID","Identifier":"0000-0003-1105-2474"},{"author:Name":"Šmíd, Břetislav","author:Affiliation":"Charles University"},{"author:Name":"Breuer, Uwe","author:Affiliation":"Forschungszentrum Jülich"},{"author:Name":"Rose, Marc-André","author:Affiliation":"Forschungszentrum Jülich"},{"author:Name":"Menzler, Norbert H.","author:Affiliation":"Forschungszentrum Jülich"},{"author:Name":"Dittmann, Regina","author:Affiliation":"Forschungszentrum Jülich"},{"author:Name":"Waser, Rainer","author:Affiliation":"Forschungszentrum Jülich"},{"author:Name":"Guillon, Olivier","author:Affiliation":"Forschungszentrum Jülich"},{"author:Name":"Gunkel, Felix","author:Affiliation":"Forschungszentrum Jülich"},{"author:Name":"Lenser, Christian","author:Affiliation":"Forschungszentrum Jülich"}],"citation:Contact":[{"datasetContact:Name":"Weber, Moritz","datasetContact:Affiliation":"Forschungszentrum Jülich","datasetContact:E-mail":"mo.weber@fz-juelich.de"},{"datasetContact:Name":"Gunkel, Felix","datasetContact:Affiliation":"Forschungszentrum Jülich","datasetContact:E-mail":"f.gunkel@fz-juelich.de"},{"datasetContact:Name":"Lenser, Christian","datasetContact:Affiliation":"Forschungszentrum Jülich","datasetContact:E-mail":"c.lenser@fz-juelich.de"}],"citation:Description":{"dsDescription:Text":"The present data repository contains all suitable data that provide the basis for the main figures of the manuscript as specified by the pulication guidelines. Accordingly, a record of text files are provided in the form of excel sheets for each relevant figure and named after the respective figure of the manuscript. Figure_1b.xlsx, Figure_2d_as-deposited_termination, Figure_2d_SrO_termination.xlsx, Figure_3d_STNNi-NbSTO.xlsx and Figure_3d_STNNi-NbSTO.xlsx contain experimental data on the properties of nanoparticles synthesized by metal exsolution as determined by evaluation of topological data obtained by atomic force microscopy. Figure_1c.xlsx contains experimental data on the cation depth profiles measured by secondary ion mass spectrometry. Figure_2a.xlsx contains XPS Ni 2p core-level spectra for different states of STNNi (different thermal oxidation / thermal reduction history and annealing time). Figure_2b.xlsx contains relative intenisty rations for the metal and oxide Ni 2p states as a function of the thermal oxidation / thermal reduction history and annealing time. Figure_2c.xlsx contains values of the space-charge induced binding energy shifts in the peak maxima of XPS O 1s, Ti 2p, Nb 3d and Sr 3d core-level recorded during consecutive thermal oxidation (p(O2) = 0.1 mbar, T = 400°C) and thermal reduction (p(H2) = 0.92 mbar, T = 400°C) steps relative to ultra high vacuum conditions. Figure_3b.xlsx and Figure_3c.xlsx contain data on the space charge potential profiles in the near-surface region of n-type STO obtained by finite-element electrostatic space charge simulations.","dsDescription:Date":"2023-10-05"},"Subject":["Chemistry","Physics"],"citation:Keyword":{"keyword:Term":"Metal exsolution, Space charge, Oxide epitaxy, Nanostructured catalysts, Nanoparticles, Solid oxide cells"},"Related Publication":{"Citation":"10.1038/s41563-023-01743-6"},"citation:Depositor":"Weber, Moritz","Deposit Date":"2023-10-05","@id":"doi:10.26165/JUELICH-DATA/CYHXRM","@type":["ore:Aggregation","schema:Dataset"],"schema:version":"1.1","schema:datePublished":"2023-11-15","schema:name":"Replication Data for: Space charge governs the kinetics of metal exsolution","schema:dateModified":"2024-01-26 10:16:38.469","schema:license":"https://creativecommons.org/publicdomain/zero/1.0/","dvcore:fileTermsOfAccess":{"dvcore:fileRequestAccess":false},"schema:includedInDataCatalog":"Peter Grünberg Institute (PGI) – Electronic Materials (PGI-7)","ore:aggregates":[{"schema:description":"The present document specifies the data which can be found in the repository and specifies the applied data treatement procedures.","schema:name":"Comment_data repository.pdf","dvcore:restricted":false,"schema:version":1,"dvcore:datasetVersionId":410,"@id":"https://data.fz-juelich.de/file.xhtml?fileId=14203","schema:sameAs":"https://data.fz-juelich.de/api/access/datafile/14203","@type":"ore:AggregatedResource","schema:fileFormat":"application/pdf","dvcore:filesize":182664,"dvcore:storageIdentifier":"s3://juelich_data:18bd0253901-702dbe0fb9ad","dvcore:rootDataFileId":-1,"dvcore:checksum":{"@type":"SHA-256","@value":"7be392838b2aa0b632c76dff9e23bac332238940e06adeb97fca634f9038c01a"}},{"schema:description":"Experimental data on the properties of nanoparticles synthesized by metal exsolution at different temperatures of T=600°C, T=700°C and T=800°C as determined by evaluation of topological data obtained by atomic force microscopy.","schema:name":"Figure_1b.xlsx","dvcore:restricted":false,"dvcore:directoryLabel":"Figure 1","schema:version":1,"dvcore:datasetVersionId":410,"@id":"https://data.fz-juelich.de/file.xhtml?fileId=12879","schema:sameAs":"https://data.fz-juelich.de/api/access/datafile/12879","@type":"ore:AggregatedResource","schema:fileFormat":"application/vnd.openxmlformats-officedocument.spreadsheetml.sheet","dvcore:filesize":867056,"dvcore:storageIdentifier":"s3://juelich_data:18affe5c9df-8ac3cd852585","dvcore:rootDataFileId":-1,"dvcore:checksum":{"@type":"SHA-256","@value":"6062cd3818a3b2145bea4b3ae0e55d52297dbc4f32226b61cb6118d2e6268d7f"}},{"schema:description":"Experimental data on the cation depth profiles measured by secondary ion mass spectrometry for an STNNi thin film after thermal reduction at T=800°C (4% H2/Ar, t = 30h). 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