{"id":12855,"identifier":"JUELICH-DATA/IFD1I9","persistentUrl":"https://doi.org/10.26165/JUELICH-DATA/IFD1I9","protocol":"doi","authority":"10.26165","publisher":"Jülich DATA","publicationDate":"2023-10-10","storageIdentifier":"s3://10.26165/JUELICH-DATA/IFD1I9","datasetVersion":{"id":397,"datasetId":12855,"datasetPersistentId":"doi:10.26165/JUELICH-DATA/IFD1I9","storageIdentifier":"s3://10.26165/JUELICH-DATA/IFD1I9","versionNumber":1,"versionMinorNumber":0,"versionState":"RELEASED","lastUpdateTime":"2023-10-10T06:24:41Z","releaseTime":"2023-10-10T06:24:41Z","createTime":"2023-09-18T10:35:24Z","license":"CCBY","fileAccessRequest":false,"metadataBlocks":{"citation":{"displayName":"Citation Metadata","fields":[{"typeName":"title","multiple":false,"typeClass":"primitive","value":"Experimental data for: Retention of 226Ra in the sandy Opalinus Clay facies from the Mont Terri rock laboratory, Switzerland"},{"typeName":"author","multiple":true,"typeClass":"compound","value":[{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Ait Mouheb, Naila"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"Institute of Energy and Climate Research – Nuclear Waste Management (IEK-6), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Yang, Yuankai"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"Institute of Energy and Climate Research – Nuclear Waste Management (IEK-6), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Deissmann, Guido"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"Institute of Energy and Climate Research – Nuclear Waste Management (IEK-6), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Klinkenberg, Martina"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"Institute of Energy and Climate Research – Nuclear Waste Management (IEK-6), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Poonoosamy, Jenna"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"Institute of Energy and Climate Research – Nuclear Waste Management (IEK-6), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Vinograd, Victor"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"Institute of Energy and Climate Research – Nuclear Waste Management (IEK-6), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Van Loon, Luc R."},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"Laboratory for Waste Management, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Bosbach, Dirk"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"Institute of Energy and Climate Research – Nuclear Waste Management (IEK-6), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany"}}]},{"typeName":"datasetContact","multiple":true,"typeClass":"compound","value":[{"datasetContactName":{"typeName":"datasetContactName","multiple":false,"typeClass":"primitive","value":"Ait Mouheb, Naila"},"datasetContactAffiliation":{"typeName":"datasetContactAffiliation","multiple":false,"typeClass":"primitive","value":"Institute of Energy and Climate Research – Nuclear Waste Management (IEK-6), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany"},"datasetContactEmail":{"typeName":"datasetContactEmail","multiple":false,"typeClass":"primitive","value":"n.ait.mouheb@fz-juelich.de"}}]},{"typeName":"dsDescription","multiple":true,"typeClass":"compound","value":[{"dsDescriptionValue":{"typeName":"dsDescriptionValue","multiple":false,"typeClass":"primitive","value":"In this study, we report results of the impact of the natural heterogeneity of sandy facies of the Opalinus clay (OPA-SF) on 226Ra uptake in drill core (BAD 1) samples from the Mont Terri underground rock laboratory. The samples were carefully characterized with respect to mineralogy and chemistry using, e.g., XRD and SEM/EDS. The uptake behaviour of 226Ra is evaluated using batch sorption experiments. \r\nThis dataset contains experimental data on a) 226Ra sorption kinetics and 226Ra sorption on sandy Opalinus Clay as a function of the S/L ratio, b) the characterization of the mineralogical composition of rock samples and the different pore-waters in equilibrium with each clay sample, c) a representation of the mineralogical composition of rock samples in a ternary diagram QFM (quartz, feldspar, and mica), and d) calculated speciation of 226Ra and saturation indices (SI) for Ra-phases in synthetic Opalinus Clay pore water and predicted mole fractions of BaSO4 and SrSO4 in (Sr,Ba)SO4 celestine solid solutions."},"dsDescriptionDate":{"typeName":"dsDescriptionDate","multiple":false,"typeClass":"primitive","value":"2023-09-18"}}]},{"typeName":"subject","multiple":true,"typeClass":"controlledVocabulary","value":["Earth and Environmental Sciences"]},{"typeName":"grantNumber","multiple":true,"typeClass":"compound","value":[{"grantNumberAgency":{"typeName":"grantNumberAgency","multiple":false,"typeClass":"primitive","value":"BMBF"},"grantNumberValue":{"typeName":"grantNumberValue","multiple":false,"typeClass":"primitive","value":"02NUK053A"}},{"grantNumberAgency":{"typeName":"grantNumberAgency","multiple":false,"typeClass":"primitive","value":"Helmholtz Association"},"grantNumberValue":{"typeName":"grantNumberValue","multiple":false,"typeClass":"primitive","value":"SO-093"}}]},{"typeName":"depositor","multiple":false,"typeClass":"primitive","value":"Ait Mouheb, Naila"},{"typeName":"dateOfDeposit","multiple":false,"typeClass":"primitive","value":"2023-09-18"}]},"fzj":{"displayName":"FZJ Metadata","fields":[{"typeName":"institute","multiple":true,"typeClass":"controlledVocabulary","value":["IEK-6"]},{"typeName":"pof4","multiple":true,"typeClass":"controlledVocabulary","value":["Nuclear Waste Disposal (POF4-1411)"]}]}},"files":[{"description":"Table A2. Calculated speciation of 226Ra (CRa = 2·10-8 mol L-1) and saturation indices (SI) for Ra-phases in synthetic Opalinus Clay pore water after Pearson (1998).","label":"Calculated speciation of 226Ra.xlsx","restricted":false,"version":1,"datasetVersionId":397,"dataFile":{"id":12858,"persistentId":"","pidURL":"","filename":"Calculated speciation of 226Ra.xlsx","contentType":"application/vnd.openxmlformats-officedocument.spreadsheetml.sheet","filesize":10318,"description":"Table A2. Calculated speciation of 226Ra (CRa = 2·10-8 mol L-1) and saturation indices (SI) for Ra-phases in synthetic Opalinus Clay pore water after Pearson (1998).","storageIdentifier":"s3://juelich_data:18aa7ea5bad-1e1e0f119cf4","rootDataFileId":-1,"checksum":{"type":"SHA-256","value":"3fe34398a94338c247459461879624fcfeb90df747203b16e645d6ac74d6ade2"},"creationDate":"2023-09-18"}},{"description":"Table A5. Experimental data of 226Ra sorption kinetics on sandy Opalinus Clay at pH 7.6 and I = 0.39 mol·L-1 (cf. Fig. 9).\r\n","label":"Experimental data of 226Ra sorption kinetics.xlsx","restricted":false,"version":1,"datasetVersionId":397,"dataFile":{"id":12861,"persistentId":"","pidURL":"","filename":"Experimental data of 226Ra sorption kinetics.xlsx","contentType":"application/vnd.openxmlformats-officedocument.spreadsheetml.sheet","filesize":11510,"description":"Table A5. Experimental data of 226Ra sorption kinetics on sandy Opalinus Clay at pH 7.6 and I = 0.39 mol·L-1 (cf. Fig. 9).\r\n","storageIdentifier":"s3://juelich_data:18aa7f31fd1-a3142753187c","rootDataFileId":-1,"checksum":{"type":"SHA-256","value":"01f2a3b2a3d71435aa89cb61e48b33b7d76370ce3c3c45903fef266bb61fb062"},"creationDate":"2023-09-18"}},{"description":"Table A6 . Experimental data of 226Ra sorption on sandy Opalinus Clay as a function of the S/L ratio at pH 7.6 and I = 0.39 mol·L-1 (cf. Fig. 12).","label":"Experimental data of 226Ra sorption on sandy Opalinus Clay as a function of the S-L ratio ","restricted":false,"version":1,"datasetVersionId":397,"dataFile":{"id":12884,"persistentId":"","pidURL":"","filename":"Experimental data of 226Ra sorption on sandy Opalinus Clay as a function of the S-L ratio ","contentType":"application/vnd.openxmlformats-officedocument.spreadsheetml.sheet","filesize":10510,"description":"Table A6 . Experimental data of 226Ra sorption on sandy Opalinus Clay as a function of the S/L ratio at pH 7.6 and I = 0.39 mol·L-1 (cf. Fig. 12).","storageIdentifier":"s3://juelich_data:18b142705ab-7190904c67d4","rootDataFileId":-1,"checksum":{"type":"SHA-256","value":"68ea1268ce1e355179728d875aa303a5a1316a96154d05cd21dd166fa15014f8"},"creationDate":"2023-10-09"}},{"description":"Table A3. Mineralogical composition (in wt.%) of rock samples from the lower sandy facies of the Opalinus Clay at Mont Terri taken from drill cores BDB-1 (Lerouge et al., 2015; Waber and Rufer, 2017) and BWS-H (Houben et al., 2014).","label":"Mineralogical composition (in wt.%) of rock samples.xlsx","restricted":false,"version":1,"datasetVersionId":397,"dataFile":{"id":12859,"persistentId":"","pidURL":"","filename":"Mineralogical composition (in wt.%) of rock samples.xlsx","contentType":"application/vnd.openxmlformats-officedocument.spreadsheetml.sheet","filesize":10979,"description":"Table A3. Mineralogical composition (in wt.%) of rock samples from the lower sandy facies of the Opalinus Clay at Mont Terri taken from drill cores BDB-1 (Lerouge et al., 2015; Waber and Rufer, 2017) and BWS-H (Houben et al., 2014).","storageIdentifier":"s3://juelich_data:18aa7ecff73-95a35b419b9f","rootDataFileId":-1,"checksum":{"type":"SHA-256","value":"b269d5b09fae86ae8bb6cb432ec76b92e1ccb8c955fe4fa185d0106f17958476"},"creationDate":"2023-09-18"}},{"description":"Table A1. Chemical composition (mol·L-1) of the different pore-waters in equilibrium with each clay sample and used in the sorption experiments in comparison to the synthetic Opalinus Clay pore water after Pearson (1998).","label":"Pore water composition.xlsx","restricted":false,"version":1,"datasetVersionId":397,"dataFile":{"id":12857,"persistentId":"","pidURL":"","filename":"Pore water composition.xlsx","contentType":"application/vnd.openxmlformats-officedocument.spreadsheetml.sheet","filesize":10522,"description":"Table A1. Chemical composition (mol·L-1) of the different pore-waters in equilibrium with each clay sample and used in the sorption experiments in comparison to the synthetic Opalinus Clay pore water after Pearson (1998).","storageIdentifier":"s3://juelich_data:18aa7e717d0-8bcca81f653b","rootDataFileId":-1,"checksum":{"type":"SHA-256","value":"87256c87ca8ef13bd5996f8c3b1dcd6b27a3a728766bbf2e022f68ba0ddfff01"},"creationDate":"2023-09-18"}},{"description":"Figure A2. Predicted mole fractions of BaSO4 and SrSO4 in (Sr,Ba)SO4 celestite solid solution, whose fraction in the system is fixed at 0.4 wt. % of the total solid.","label":"Predicted mole fractions of BaSO4 and SrSO4.docx","restricted":false,"version":1,"datasetVersionId":397,"dataFile":{"id":12864,"persistentId":"","pidURL":"","filename":"Predicted mole fractions of BaSO4 and SrSO4.docx","contentType":"application/vnd.openxmlformats-officedocument.wordprocessingml.document","filesize":21510,"description":"Figure A2. Predicted mole fractions of BaSO4 and SrSO4 in (Sr,Ba)SO4 celestite solid solution, whose fraction in the system is fixed at 0.4 wt. % of the total solid.","storageIdentifier":"s3://juelich_data:18aa80ed81e-e6f12f51969a","rootDataFileId":-1,"checksum":{"type":"SHA-256","value":"743b8a35fa0eccd586baabe0538b3916c658ea3027a60d42db0afb64222956eb"},"creationDate":"2023-09-18"}},{"description":"Figure A1. (Left) Representation of the mineralogical composition of rock samples from the lower sandy Opalinus Clay facies from drill core BAD-1 in a ternary diagram QFM (quartz, feldspar, and mica) – clay minerals – carbonates; (Right) lithotype classification of organic mudstones based on their mineralogical composition after Gamero-Diaz et al. (2013) and Glaser et al. (2014).","label":"Representation of the mineralogical composition of rock samples.docx","restricted":false,"version":1,"datasetVersionId":397,"dataFile":{"id":12863,"persistentId":"","pidURL":"","filename":"Representation of the mineralogical composition of rock samples.docx","contentType":"application/vnd.openxmlformats-officedocument.wordprocessingml.document","filesize":338388,"description":"Figure A1. (Left) Representation of the mineralogical composition of rock samples from the lower sandy Opalinus Clay facies from drill core BAD-1 in a ternary diagram QFM (quartz, feldspar, and mica) – clay minerals – carbonates; (Right) lithotype classification of organic mudstones based on their mineralogical composition after Gamero-Diaz et al. (2013) and Glaser et al. (2014).","storageIdentifier":"s3://juelich_data:18aa80df6db-ef014c3b3791","rootDataFileId":-1,"checksum":{"type":"SHA-256","value":"c5d4953e1df4cf6111f43daa20b3527a97c4b2d67c57f584365f342ef0aabdb4"},"creationDate":"2023-09-18"}},{"description":"Table A4. Result of EDS spot analyses of (Ba, Sr)-sulphate from the lower sandy Opalinus Clay facies (cf. Fig. 8).\r\n","label":"Result of EDS spot analyses of (Ba, Sr)-sulphate.xlsx","restricted":false,"version":1,"datasetVersionId":397,"dataFile":{"id":12860,"persistentId":"","pidURL":"","filename":"Result of EDS spot analyses of (Ba, Sr)-sulphate.xlsx","contentType":"application/vnd.openxmlformats-officedocument.spreadsheetml.sheet","filesize":9754,"description":"Table A4. Result of EDS spot analyses of (Ba, Sr)-sulphate from the lower sandy Opalinus Clay facies (cf. Fig. 8).\r\n","storageIdentifier":"s3://juelich_data:18aa7efbfdb-2548e060cf92","rootDataFileId":-1,"checksum":{"type":"SHA-256","value":"df39db1e70cb4d95f48de2e93ca0d699f53a84b4125dfddcc9efd8a1d574bb58"},"creationDate":"2023-09-18"}}],"citation":"Ait Mouheb, Naila; Yang, Yuankai; Deissmann, Guido; Klinkenberg, Martina; Poonoosamy, Jenna; Vinograd, Victor; Van Loon, Luc R.; Bosbach, Dirk, 2023, \"Experimental data for: Retention of 226Ra in the sandy Opalinus Clay facies from the Mont Terri rock laboratory, Switzerland\", https://doi.org/10.26165/JUELICH-DATA/IFD1I9, Jülich DATA, V1"}}